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Di-mu-sulfido-bis[diaqua(18-crown-6)barium(II)]-saccharin (1/2)
Suchada Chantrapromma1, Anwar Usman, Hoong Kun Fun
1Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat-Yai, Songkhla 90112, Thailand.
Abstract:
The molecule of the title compound [systematic name: di-mu-sulfido-bis[diaqua(1,4,7,10,13,16-hexaoxacyclooctadecane-kappa(6)O)barium(II)] bis[1,2-benzisothiazol-3(2H)-one 1,1-dioxide]], [Ba(2)S(2)(C(12)H(24)O(6))(2)(H(2)O)(4)](C(7)H(5)NO(3)S)(2), lies on an inversion centre. The Ba(II) atom encapsulated by the 18-crown-6 ring is coordinated by the six O atoms of the crown, two water O atoms and two bridging S atoms. The four-membered ring composed of the Ba(II) atoms and the bridging S atoms makes a dihedral angle of 67.1 (1) degrees with the crown-ether ring. The aromatic ring system of the saccharin moiety is essentially planar. The packing is built up from layers of the molecules and is stabilized by three intermolecular O-H.O hydrogen bonds.
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