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Stereoselective intermolecular carboazidation of chiral allylsilanes
Laurent Chabaud1, Yannick Landais, Philippe Renaud
1Université de Bordeaux 1, Laboratoire de Chimie Organique et Organométallique, 351, Cours de la Libération, F-33405 Talence Cedex, France.
Organic Letters
|November 22, 2002
Abstract:
[reaction: see text] Easily available chiral allylsilanes were used as substrate for carboazidation reactions. For the first time, a substantial control of the stereochemistry of the azidation of acyclic nonconjugated radicals was achieved.