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Adsorption mode of cinchonidine on Cu(111) surface
Qing-Min Xu1, Dong Wang, Li-Jun Wan
1Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
Abstract:
The adsorption mode of cinchonidine on Cu(111) was directly obtained by in situ STM. The molecules were found to adsorb on the substrate surface and form a long-range ordered adlayer with (4 x 4) symmetry. While the quinoline rings lie parallel to Cu(111), the chiral quinuclidine moiety extends out of the surface. The enantioselectivity of catalysts may relate to this special adsorption conformation of cinchonidine on the surface.
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