Related Experiment Video
Updated: Jul 7, 2026

Isothermal Titration Calorimetry for Measuring Macromolecule-Ligand Affinity
Published on: September 7, 2011
Thermodynamic product retrieval methodology and validation for NAST-I
Daniel K Zhou1, William L Smith, Jun Li
1Atmospheric Science Competency, NASA Langley Research Center, Hampton, Virginia 23681, USA. d.k.zhou@larc.nasa.gov
Abstract:
The National Polar-Orbiting Operational Environmental Satellite System (NPOESS) Airborne Sounder Testbed (NAST) consists of two passive collocated cross-track scanning instruments, an infrared interferometer (NAST-I) and a microwave radiometer (NAST-M), that fly onboard high-altitude aircraft such as the NASA ER-2 at an altitude near 20 km. NAST-I provides relatively high spectral resolution (0.25-cm(-1)) measurements in the 645-2700-cm(-1) spectral region with moderate spatial resolution (a linear resolution equal to 13% of the aircraft altitude at nadir) cross-track scanning. We report the methodology for retrieval of atmospheric temperature and composition profiles from NAST-I radiance spectra. The profiles were determined by use of a statistical eigenvector regression algorithm and improved, as needed, by use of a nonlinear physical retrieval algorithm. Several field campaigns conducted under varied meteorological conditions have provided the data needed to verify the accuracy of the spectral radiance, the retrieval algorithm, and the scanning capabilities of this instrumentation. Retrieval examples are presented to demonstrate the ability to reveal fine-scale horizontal features with relatively high vertical resolution.
Related Concept Videos
Thermal Sigmatropic Reactions: Overview
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in 1,5-hexadiene, referred to as...
Thermodynamic Systems
Consider an example of tea boiling in a kettle. The tea and...
Thermodynamic Potentials
Thermodynamics: Chemical Potential and Activity
The thermodynamic equilibrium constant is more accurately defined in terms of activity rather than concentration.
Thermodynamics: Activity Coefficient
The activity coefficient is a measure of the deviation from ideal behavior. When the ionic strength of the solution is minimal, the activity coefficient of an ionic species is close to unity, making...
Thermodynamic Processes

