Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

Ammonium 4-nitrophenylarsonate.

Jin Yang1, Jian Fang Ma, Ying Chun Liu

  • 1Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.

Acta Crystallographica. Section C, Crystal Structure Communications
|December 6, 2002
PubMed
Summary

The crystal structure reveals ammonium cations and 4-nitrophenylarsonate anions forming chains via hydrogen bonds. The hydroxyl group on the anion plays a dual role in this hydrogen bonding network.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Interleukin-37 suppresses tumor growth through inhibition of angiogenesis in non-small cell lung cancer.

Journal of experimental & clinical cancer research : CR·2016
Same author

Iodine Status of Vulnerable Populations in Henan Province of China 2013-2014 After the Implementation of the New Iodized Salt Standard.

Biological trace element research·2016
Same author

Establishment and comparison of three novel methods for the determination of the photodynamic therapy agent 2-[1-hexyloxyethyl]-2-devinyl pyropheophorbide-a (HPPH) in human serum.

Journal of pharmaceutical and biomedical analysis·2016
Same author

HPLC-MS/MS method for the simultaneous determination of MB07133 and its metabolites, cytarabine and arabinofuranosyluracil, in rat plasma.

Journal of pharmaceutical and biomedical analysis·2016
Same author

Bioactive Enmein-Type ent-Kaurane Diterpenoids from Isodon phyllostachys.

Journal of natural products·2016
Same author

[Association between negative emotion and interpersonal sensitivity among patients in methadone maintenance treatment].

Zhonghua yu fang yi xue za zhi [Chinese journal of preventive medicine]·2016

Area of Science:

  • Inorganic Chemistry
  • Crystallography
  • Materials Science

Background:

  • Understanding the structural properties of organoarsenic compounds is crucial for their application.
  • Hydrogen bonding plays a significant role in the assembly of crystal structures.
  • Ammonium salts with complex anions offer diverse structural motifs.

Purpose of the Study:

  • To elucidate the crystal structure of ammonium 4-nitrophenylarsonate.
  • To investigate the hydrogen bonding interactions within the crystal lattice.
  • To characterize the coordination environment of the arsenic atom.

Main Methods:

  • Single-crystal X-ray diffraction was employed to determine the crystal structure.
  • Analysis of bond lengths, bond angles, and hydrogen bond distances.

Related Experiment Videos

  • Identification of donor and acceptor atoms in the hydrogen bonding network.

    • Main Results:

    • The crystal structure consists of ammonium cations and 4-nitrophenylarsonate anions.
    • Infinite chains are formed along the b axis through intermolecular hydrogen bonds.
    • The hydroxyl oxygen atom of the arsonate anion acts as both a hydrogen bond donor and acceptor.

    Conclusions:

    • The hydrogen bonding network dictates the one-dimensional chain structure.
    • The hydroxyl group's amphoteric hydrogen bonding capability is key to the observed structure.
    • The compound exhibits a well-defined crystal structure with atoms in general positions.