Stereoselective C-glycosidation of unprotected D-glycals with trimethylsilyl cyanide
Masahiko Hayashi1, Hirotoshi Kawabata, Shu-Zo Nakayama
1Department of Chemistry, Faculty of Science, Kobe University, Nada, Kobe, Japan. mhayashi@kobe-u.ac.jp
Chirality
|December 6, 2002
Abstract:
Unprotected glycals reacted with trimethylsilyl cyanide in the presence of a catalytic amount of a palladium compound to yield the 2,3-unsaturated glycosyl cyanides in high yield and in alpha-selectivity.
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