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The origin of electrochemical activity in Li2MnO3
Alastair D Robertson1, Peter G Bruce
1School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland, UK KY16 9ST.
Abstract:
The electrochemical activity of Li2MnO3 in non-aqueous media has been investigated and found to involve neither Mn(4+)-Mn5+ oxidation nor simultaneous O2- removal but exchange of Li+ by H+, the latter being generated in the electrolyte.