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A proton induced conformational change in metal complexes with potential hydrogen bonding triplet motifs
Ian M Atkinson1, Michael M Bishop, Leonard F Lindoy
1James Cook University, Townsville, Australia. ian.atkinson@jcu.edu.au
Chemical Communications (Cambridge, England)
|December 14, 2002
Abstract:
Biguanide-like bidentate ligands in a variety of transition metal complexes of different geometries exhibit conformational changes upon protonation/deprotonation that alter their capacity to recognise complementary hydrogen bonding motifs.