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Self-assembly of a twelve-component hexanuclear metallomacrocycle constructed with a novel tri-amino ligand
Georg Seeber1, Benson Kariuki, Leroy Cronin
1Department of Chemistry, University of Glasgow, University Avenue, Glasgow, UK G12 8QQ.
Chemical Communications (Cambridge, England)
|December 14, 2002
Abstract:
Reaction of the novel ligand cis,trans-1,3,5-triaminocyclohexane, which contains two types of metal binding sites trans to each other, with palladium(II) chloride results in the self assembly of a hexanuclear ring cluster that has been characterised both in the solid state and in solution.