Ehrenfest-time-dependent excitation gap in a chaotic Andreev billiard

A semiclassical theory is developed for the appearance of an excitation gap in a ballistic chaotic cavity connected by a point contact to a superconductor. Diffraction at the point contact is a singular perturbation in the limit variant Planck's over 2pi -->0, which opens up a gap E(gap) in the excitation spectrum. The time scale variant Planck's over 2pi /E(gap) proportional, variant alpha(-1)ln( variant Planck's over 2pi (with alpha the Lyapunov exponent) is the Ehrenfest time, the characteristic time scale of quantum chaos.