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Zwitterionic 5-(1-piperidiniomethyl)-1H-tetrazolide
Alexander S Lyakhov1, Sergei V Voitekhovich, Pavel N Gaponik
1Physico-Chemical Research Institute, Belarusian State University, Leningradskaya Str 14, Minsk 220050, Belarus. lyakhov@bsu.by
Acta Crystallographica. Section C, Crystal Structure Communications
|December 31, 2002
Abstract:
The title compound, C(7)H(13)N(5), a tetrazole analogue of betaines, exists as a zwitterion, with the H atom of the tetrazole ring being transferred to the piperidine ring N atom. The tetrazole ring symmetry is close to C(2v), which suggests strong charge delocalization in the N-C-N fragment of the ring. There are classical hydrogen bonds in the structure which are responsible for the formation of two-membered aggregates.