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Updated: Aug 10, 2026

Cooling Rate Dependent Ellipsometry Measurements to Determine the Dynamics of Thin Glassy Films
Published on: January 26, 2016
Thermal glass transition beyond the Vogel-Fulcher-Tammann behavior for glass forming diglycidylether of bisphenol A
J K Krüger1, T Britz, J Baller
1Laboratoire Européen de Recherche Universitaire Saarland-Lorraine, Germany. jk.krueger@mx.uni-saarland.de
Abstract:
For the low molecular weight fragile liquid diglycidyl ether of bisphenol A we report, based on Brillouin and dielectric spectroscopy, on a thermal glass transition where the relaxation time of the alpha process does not go to infinity. Instead, the structural alpha relaxation disappears spontaneously at the transition point. That discontinuity in relaxation time coincides with a kink in the longitudinal hypersonic velocity and determines unambiguously the transition from the liquid to the glassy state.
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