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Updated: Aug 20, 2026

Confocal Imaging of Confined Quiescent and Flowing Colloid-polymer Mixtures
Published on: May 20, 2014
Molecular hydrodynamic theory of supercooled liquids and colloidal suspensions under shear
Kunimasa Miyazaki1, David R Reichman
1Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, USA. miyazaki@fas.harvard.edu
Abstract:
We extend the conventional mode-coupling theory of supercooled liquids to systems under stationary shear flow. Starting from generalized fluctuating hydrodynamics, a nonlinear equation for the intermediate scattering function is constructed. We evaluate the solution numerically for a model of a two-dimensional colloidal suspension and find that the structural relaxation time decreases as gamma;(-nu) with an exponent nu=1, where gamma; is the shear rate. The results are in qualitative agreement with recent molecular dynamics simulations. We discuss the physical implications of the results.
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