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The Synthesis of [Sn10(Si(SiMe3)3)4]2- Using a Metastable Sn(I) Halide Solution Synthesized via a Co-condensation Technique
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Synthesis and structural characterization of a new open-framework tin(II) phosphate: [Sn4(PO4)3]-.0.5[C4N2H12]2+

Y L Liu1, G S Zhu, J S Chen

  • 1Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun 130023, China.

Inorganic Chemistry
|January 16, 2003
PubMed
Abstract

No abstract available in PubMed .

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Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...

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