Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Experiment Videos

A potassium selective 'nanosponge' with well defined pores.

Achim Müller1, Bogdan Botar, Hartmut Bögge

  • 1Fakultät für Chemie der Universität, Lehrstuhl für Anorganische Chemie 1, Postfach 100131, D 33501 Bielefeld, Germany. a.mueller@uni-bielefeld.de

Chemical Communications (Cambridge, England)
|January 23, 2003
PubMed
Summary

A new spherical cluster-compound containing molybdenum and vanadium was synthesized using a single-step reaction. This novel material features 30 open-shell centers within an icosidodecahedron, K+ cations, and encapsulated water molecules.

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

Electrically Controlled Excitons, Charge Transfer Induced Trions, and Narrowband Emitters in MoSe<sub>2</sub>-WSe<sub>2</sub> Lateral Heterostructure.

Nano letters·2024
Same author

Cold and Liquid Crystal Properties of Square-Planar Copper(II) Versus Nickel(II)- Iminophenolate/Naphthalen-2-Olate Schiff Base Complexes.

Chemistry, an Asian journal·2024
Same author

Increasing the electron donation in a dinucleating ligand family: molecular and electronic structures in a series of Co<sup>II</sup>Co<sup>II</sup> complexes.

Dalton transactions (Cambridge, England : 2003)·2024
Same author

Coordination-triggered redox activity of early and late lanthanide calix[4]arene complexes.

Dalton transactions (Cambridge, England : 2003)·2024
Same author

Tandem templating strategies facilitate the assembly of calix[8]arene-supported Ln<sub>18</sub> clusters.

Dalton transactions (Cambridge, England : 2003)·2024
Same author

Infrared Resonance Raman of Bilayer Graphene: Signatures of Massive Fermions and Band Structure on the 2D Peak.

Nano letters·2024

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Solid-State Chemistry

Background:

  • Cluster compounds represent a fascinating area of inorganic chemistry, offering unique structural and electronic properties.
  • The synthesis of complex polyoxometalates often requires multi-step procedures, limiting their accessibility.

Purpose of the Study:

  • To synthesize a novel spherical cluster-compound with remarkable structural complexity.
  • To characterize the structural features, including open-shell centers and cation incorporation, of the new compound.

Main Methods:

  • A 'one-pot' synthetic approach was employed for the preparation of the cluster-compound.
  • Structural characterization was performed using X-ray diffraction and other analytical techniques (details not provided in the abstract).

Related Experiment Videos

Main Results:

  • A novel spherical cluster-compound, K2Na6[K20[Mo80-V22O282(SO4)12(H2O)66]]·~140H2O, was successfully synthesized.
  • The compound exhibits an icosidodecahedral framework containing 30 open-shell centers (8 Mo(V) and 22 V(IV)).
  • The structure incorporates 20 K+ cations capping surface pores and an encapsulated water molecule aggregate.

Conclusions:

  • The 'one-pot' synthesis provides an efficient route to complex spherical cluster-compounds.
  • The unique structural features, including the high density of open-shell centers and specific cation/water encapsulation, offer potential for novel applications in catalysis or magnetism.