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New routes to high nuclearity cages: a fluoride-based hexaicosametallic manganese cage
Leigh F Jones1, Euan K Brechin, David Collison
1Department of Chemistry, University of Manchester, Oxford Road, Manchester, UK M13 9PL.
Chemical Communications (Cambridge, England)
|January 23, 2003
Abstract:
The reaction of MnF3 with benzotriazole (BTAH) in hot MeOH gives the Mn(III) complex [Mn26O16(OH)10(OMe)6(F)10(BTA)20(BTAH)2(MeOH)13(H2O)] which displays hysteresis and temperature-independent magnetisation relaxation at low temperature.