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Synthesis and structure of an asymmetric copper(I) dimer with two-coordinate and four-coordinate copper(I) sites
Yi Liao1, Juan J Novoa, Atta Arif
1Department of Chemistry, University of Utah, Salt Lake City, UT 84112-0850, USA.
Chemical Communications (Cambridge, England)
|January 23, 2003
Abstract:
An asymmetric copper(I) dimer Cu(1)2(pip)2 [pip = (2-picolyliminomethyl)pyrrole anion] with both two-coordinate and four-coordinate copper(I) sites was synthesized and studied by X-ray diffraction and DFT calculations.