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Switchable thiophene coordination in Ru(II) bipyridyl phosphinoterthiophene complexes
Carolyn Moorlag1, Olivier Clot, Michael O Wolf
1Department of Chemistry, University of British Columbia, 2036 Main Mall, Vancouver, Canada V6T 1Z1.
Chemical Communications (Cambridge, England)
|January 23, 2003
Abstract:
Switching between P,S- and P,C coordination modes of 3'-phosphinoterthiophene to Ru(II) results in substantial differences in the electronic spectra and cyclic voltammetry of these complexes.