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Related Concept Videos

Photoelectric Effect02:26

Photoelectric Effect

When light of a particular wavelength strikes a metal surface, electrons are emitted. This is called the photoelectric effect. The minimum frequency of light that can cause such emission of electrons is called the threshold frequency, which is specific to the metal. Light with a frequency lower than the threshold frequency, even if it is of high intensity, cannot initiate the emission of electrons. However, when the frequency is higher than the threshold value, the number of electrons ejected...
Voltaic/Galvanic Cells02:47

Voltaic/Galvanic Cells

Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
Thermal and Photochemical Electrocyclic Reactions: Overview01:26

Thermal and Photochemical Electrocyclic Reactions: Overview

Electrocyclic reactions are reversible reactions. They involve an intramolecular cyclization or ring-opening of a conjugated polyene. Shown below are two examples of electrocyclic reactions. In the first reaction, the formation of the cyclic product is favored. In contrast, in the second reaction, ring-opening is favored due to the high ring strain associated with cyclobutene formation.
Photoluminescence: Applications01:14

Photoluminescence: Applications

Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...
P-N junction01:11

P-N junction

A p-n junction is formed when p-type and n-type semiconductor materials are joined together. At the interface of the p-n junction, holes from the p-side and electrons from the n-side begin to diffuse into the opposite sides due to the concentration gradient. This diffusion of carriers leads to a region around the junction where there are no free charge carriers, known as the depletion region. The charge density within the depletion region for the n-side and p-side can be described by the...
Schottky Barrier Diode01:27

Schottky Barrier Diode

Schottky barrier diodes are specialized semiconductor devices characterized by their unique construction. This construction involves combining a metal layer with a moderately doped n-type semiconductor material. This combination leads to the formation of a Schottky barrier, a pivotal element that defines the diode's operational characteristics. The core functionality of Schottky barrier diodes is their capacity to allow current to flow in only one direction due to their distinctive...

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Related Experiment Video

Updated: Jun 23, 2026

Fabrication of Fully Solution Processed Inorganic Nanocrystal Photovoltaic Devices
11:06

Fabrication of Fully Solution Processed Inorganic Nanocrystal Photovoltaic Devices

Published on: July 8, 2016

A photovoltaic device structure based on internal electron emission.

Eric W McFarland1, Jing Tang

  • 1Department of Chemical Engineering, University of California, Santa Barbara, California 93106-5080, USA. mcfar@engineering.ucsb.edu

Nature
|February 7, 2003
PubMed
Summary

Researchers developed a novel multilayer photovoltaic device where light absorption occurs on photoreceptors, enabling efficient electron transfer for solar energy conversion. This approach offers a promising path toward durable, low-cost solar cells.

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Area of Science:

  • Materials Science
  • Solid-State Physics
  • Renewable Energy

Background:

  • Conventional solar cells rely on bulk semiconductor absorption and electric fields for charge separation.
  • The search for cost-effective and efficient photovoltaic devices has been ongoing since the 1950s.
  • Existing technologies face challenges in cost, durability, and efficiency.

Purpose of the Study:

  • To introduce a novel multilayer photovoltaic device structure.
  • To explore an alternative mechanism for photovoltaic energy conversion.
  • To demonstrate the potential for low-cost, durable solar cells.

Main Methods:

  • Fabrication of a multilayer device with photoreceptors on an ultrathin metal-semiconductor junction Schottky diode.
  • Utilizing ballistic electron transport over a Schottky barrier for photocurrent generation.
  • Characterization of device performance under visible light illumination.

Main Results:

  • Photon absorption occurs in surface photoreceptors, not the semiconductor.
  • Photoexcited electrons travel ballistically through noble metals to the Schottky barrier.
  • Devices achieved open-circuit photovoltages of 600-800 mV and photocurrents of 10-18 micro A cm(-2).
  • Internal quantum efficiency reached 10%.

Conclusions:

  • This alternative photovoltaic approach utilizes surface absorption and ballistic electron transport.
  • The semiconductor's role is limited to majority charge transport and separation.
  • The proposed structure offers potential for developing durable, low-cost solar cells from diverse materials.