Related Experiment Videos
Chemoselective radical cleavage of Cbz-protected nitrogen compounds
M-Lluïsa Bennasar1, Tomàs Roca, Ariadna Padullés
1Laboratory of Organic Chemistry, Faculty of Pharmacy, University of Barcelona, Barcelona 08028, Spain. bennasar@farmacia.far.ub.es
Organic Letters
|February 14, 2003
Abstract:
[reaction: see text] Tributylstannyl radicals promote the deprotection of N-Cbz derivatives of amides and nitrogen-containing heteroaromatic rings. These radical conditions do not affect N-Cbz derivatives of basic amines.