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Further reactions of phenyldimethylsilyllithium with N,N-dimethylamides
Ian Fleming1, Matthew G Russell
1Department of Chemistry, Lensfield Road, Cambridge, UK CB2 1EW. if10000@cam.ac.uk
Chemical Communications (Cambridge, England)
|February 15, 2003
Abstract:
Phenyldimethylsilyllithium reacts with several N,N-dimethylamides, and the intermediates, formulated here as successively a carbene and an alpha-silyllithium species, may be trapped with nucleophiles and electrophiles, respectively, although not always with the nucleophile or electrophile of your choice.