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Fast peroxyoxalate chemiluminescence for minimized analytical separation systems
Ji Hoon Lee1, Jongtae Je, Mark A Schlautmana
1Department of Environmental Toxicology and the Clemson Institute of Environmental Toxicology, Clemson University, Pendleton, SC 29670, USA. lee@clemson.edu
Chemical Communications (Cambridge, England)
|February 15, 2003
Abstract:
The maximum intensity, Imax, and time required to reach the maximum emission, taumax, for 1-aminopyrene monitored in 1,1'-oxalyldi-4-methylimidazole (OD4MI) chemiluminescence (CL) reactions are approximately 61 times higher and 16 times faster than their respective values for bis(2,4,6-trichlorophenyl)oxalate (TCPO) CL reactions in the presence of imidazole (ImH).