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First synthesis of perfluorinated corrole and its mn=o complex
Hai-Yang Liu1, Tat-Shing Lai, Lam-Lung Yeung
1Department of Chemistry, Lab of Chemical Biology, Inst. of Molecular Technology for Drug Discovery and Synthesis, Hong Kong Univ. of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China.
Organic Letters
|February 28, 2003
Abstract:
A novel perfluorinated corrole, 2,3,7,8,12,13,17,18-octafluoro-5,10,15-tris(pentafluorophenyl)corrole, and its manganese(III) and oxomanganese(V) derivatives have been synthesized. The perfluorinated manganese corrolate exhibited excellent reactivity and stability in the catalytic oxidation of alkenes with iodosylbenzene.