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Chiral quantification of D-, L-, and meso-tartaric acid mixtures using a mass spectrometric kinetic method
Lianming Wu1, Rebecca L Clark, R Graham Cooks
1Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA.
Abstract:
Accurate quantification of the optical isomers in a ternary mixture of D-, L-, and meso-tartaric acids is achieved using electrospray ionization tandem mass spectrometry for in-situ metal complex formation and a three-point calibration method to quantify the dissociation kinetics.