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Dioxygen activation by a dinuclear nickel thiolate complex: structural characterization of the ligand oxidized
Todd C Harrop1, Marilyn M Olmstead, Pradip K Mascharak
1Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064, USA.
Chemical Communications (Cambridge, England)
|March 5, 2003
Abstract:
A (mu-SR)2-nickel(II) dimer derived from a ligand with carboxamido nitrogen and thiolato sulfur donors reacts with O2 to afford an oxidized product in which phenyl groups of the ligand frames are oxidized to nickel-bound phenolates.