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Electrophoretic mobility of a charged cylindrical colloidal particle covered with an ion-penetrable uncharged polymer
1Faculty of Pharmaceutical Sciences and Institute of Colloid and Interface Science, Science University of Tokyo, 12 Ichigaya Funagawara-machi, Shinjuku-ku, Tokyo 162-0826, Japan. ohshima@ps.kagu.sut.ac.jp
Journal of Colloid and Interface Science
|March 6, 2003
Abstract:
Expressions are derived for the electrophoretic mobility of a cylindrical charged colloidal particle carrying a low zeta potential covered with an ion-penetrable uncharged polymer layer in an electrolyte solution. These expressions involve numerical integration of modified Bessel functions but are easily calculable with Mathematica. The obtained mobility expressions are a modification of Henry's mobility formula for a cylindrical particle taking into account the presence of the uncharged polymer layer.