Related Experiment Video
Updated: Aug 13, 2026

08:51
Coulomb Explosion Imaging as a Tool to Distinguish Between Stereoisomers
Published on: August 18, 2017
New shape isomer in the self-conjugate nucleus 72Kr
Physical Review Letters
|March 14, 2003
Summary
Researchers discovered a new excited state in the self-conjugate nucleus 72Kr, providing the first evidence of a shape isomer in N=Z nuclei. This finding clarifies the nuclear shape of 72Kr, revealing an oblate-deformed ground state.
Area of Science:
- Nuclear Physics
- Atomic Physics
Background:
- The study of nuclear structure in self-conjugate (N=Z) nuclei is crucial for understanding fundamental nuclear forces.
- Identifying isomeric states and their decay properties provides insights into nuclear shapes and configurations.
- Previous research on 72Kr suggested complex nuclear structure, but experimental evidence for shape isomerism was lacking.
Purpose of the Study:
- To identify and characterize new excited states in the self-conjugate nucleus 72Kr.
- To investigate the electric-monopole decay of isomeric states in 72Kr.
- To provide the first experimental evidence for shape isomerism in an N=Z nucleus.
Main Methods:
- Utilized a combination of conversion-electron and gamma-ray spectroscopy.
- Employed high-energy fragmentation techniques to produce metastable states.
- Analyzed decay properties to establish the nature of the new isomeric state.
Main Results:
- Identified a new isomeric 0(+) state as the first excited state in 72Kr.
- Established the electric-monopole decay of this new isomer to the ground state.
- Interpreted the new 0(+) state as the band head of a prolate rotational structure.
Conclusions:
- The findings strongly support the interpretation of 72Kr possessing an oblate-deformed ground state.
- This work presents the first evidence for a shape isomer in a self-conjugate (N=Z) nucleus.
- The observed shape isomerism in 72Kr offers new perspectives on nuclear structure theories.
Related Concept Videos
Nuclear Stability
Protons and neutrons, collectively called nucleons, are packed together tightly in a nucleus. With a radius of about 10−15 meters, a nucleus is quite small compared to the radius of the entire atom, which is about 10−10 meters. Nuclei are extremely dense compared to bulk matter, averaging 1.8 × 1014 grams per cubic centimeter. If the earth’s density were equal to the average nuclear density, the earth’s radius would be only about 200 meters.
To hold positively charged protons together in the...
To hold positively charged protons together in the...
Electrophilic Addition to Alkynes: Halogenation
Introduction
Halogenation is another class of electrophilic addition reactions where a halogen molecule gets added across a π bond. In alkynes, the presence of two π bonds allows for the addition of two equivalents of halogens (bromine or chlorine). The addition of the first halogen molecule forms a trans-dihaloalkene as the major product and the cis isomer as the minor product. Subsequent addition of the second equivalent yields the tetrahalide.
Halogenation is another class of electrophilic addition reactions where a halogen molecule gets added across a π bond. In alkynes, the presence of two π bonds allows for the addition of two equivalents of halogens (bromine or chlorine). The addition of the first halogen molecule forms a trans-dihaloalkene as the major product and the cis isomer as the minor product. Subsequent addition of the second equivalent yields the tetrahalide.
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution
At room temperature, the chair conformer of cyclohexane undergoes rapid ring flipping between two equivalent chair conformers at a rate of approximately 105 times per second. These two chair conformers are in equilibrium. The rapid ring flipping results in the interconversion of the axial proton to an equatorial proton and an equatorial to the axial proton. Such interconversions are too rapid and cannot be detected on the NMR timescale. Hence, the NMR spectrometer cannot distinguish between the...
Atomic Nuclei: Nuclear Spin
All atomic particles possess an intrinsic angular momentum, or 'spin'. Electrons, protons, and neutrons each have a spin value of ½, although protons and neutrons in nuclei may have higher half-integer spins owing to energetic factors.
Atomic nuclei have a net nuclear spin, , which can have an integer or half-integer value. In atomic nuclei, the spins of protons are paired against each other but not with neutrons, and vice versa. Consequently, an even number of protons does not contribute to...
Atomic nuclei have a net nuclear spin, , which can have an integer or half-integer value. In atomic nuclei, the spins of protons are paired against each other but not with neutrons, and vice versa. Consequently, an even number of protons does not contribute to...
Atomic Nuclei: Nuclear Spin State Population Distribution
Near absolute zero temperatures, in the presence of a magnetic field, the majority of nuclei prefer the lower energy spin-up state to the higher energy spin-down state. As temperatures increase, the energy from thermal collisions distributes the spins more equally between the two states. The Boltzmann distribution equation gives the ratio of the number of spins predicted in the spin −½ (N−) and spin +½ (N+) states.
Other Nuclides: 31P, 19F, 15N NMR
Many organic, inorganic, and biological molecules contain spin-half nuclei such as nitrogen-15, fluorine-19, and phosphorus-31. As a result, NMR studies of these nuclei have found extensive applications in chemical and biological research.
While fluorine-19 and phosphorous-31 have high natural abundances (100%) and positive gyromagnetic ratios, nitrogen-15 has a low natural abundance and a negative gyromagnetic ratio. However, nitrogen-15 is still preferred over nitrogen-14 (which has a high...
While fluorine-19 and phosphorous-31 have high natural abundances (100%) and positive gyromagnetic ratios, nitrogen-15 has a low natural abundance and a negative gyromagnetic ratio. However, nitrogen-15 is still preferred over nitrogen-14 (which has a high...

