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Repulsive step potential: a model for a liquid-liquid phase transition
Valentin N Ryzhov1, Sergei M Stishov
1Institute for High Pressure Physics, Russian Academy of Sciences, 142190 Troitsk, Moscow Region, Russia.
Abstract:
In the framework of the perturbation theory for fluids we study the model with the isotropic repulsive step potential which in addition to the hard core has a repulsive soft core of a larger radius. It is shown that this purely repulsive potential is sufficient to explain a liquid-liquid phase transition and liquid anomalies.