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The first NH aldimine organometallic compound. Isolation and crystal structure
Joan Albert1, J Magali Cadena, Asensio González
1Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028 Barcelona, Spain.
Chemical Communications (Cambridge, England)
|March 18, 2003
Abstract:
The first NH aldimine organometallic derivative is unexpectedly formed by the cleavage of the nitrogen-carbon bond of the amino acid fragment of the Schiff base 2,4,6-Me3C6H2CH=NCH(CH2Ph)COOEt when the imine is treated with palladium acetate.