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Updated: Aug 10, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
New Rh(I) and Rh(III) bisimidazol-2-ylidene complexes: synthesis, reactivity, and molecular structures
Macarena Poyatos1, Mercedes Sanaú, Eduardo Peris
1Departamento de Química Inorgánica y Orgánica, Universitat Jaume I, 12080 Castellón, Spain.
Abstract:
New chelate bis-heterocyclic-carbene complexes of Rh(I) and Rh(III) have been obtained and fully characterized. The molecular structures of the new species have been determined. The synthesis of the compounds starts from the bisimidazolium precursors, which are deprotonated with NEt(3) under mild reaction conditions, leading to coordination to the Rh complex. The Rh(III) compounds are generated from Rh(I) and [Rh(II)](2) species, although there is no apparent oxidizing agent in the reaction media.
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