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Structural and magnetic properties of a self-assembled spheroidal triakonta-hexanuclear Cu36 cluster
Tareque S M Abedin1, Laurence K Thompson, David O Miller
1Deparment of Chemistry, Memorial University, St. John's, NL, Canada A1B 3X7.
Chemical Communications (Cambridge, England)
|April 22, 2003
Abstract:
An extended tritopic picolinic dihydrazide ligand with terminal oxime groups (dpocco) undergoes spontaneous self-assembly in the presence of copper acetate to produce a unique Cu36 cluster exhibiting intramolecular anti-ferromagnetic exchange.