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Migratory insertion in N-heterocyclic carbene complexes of palladium; an experimental and DFT study
Andreas A Danopoulos1, Nikolaos Tsoureas, Jennifer C Green
1Department of Chemistry, University of Southampton, Highfield, Southampton, UK S017 1BJ. d1@soton.ac.uk
Chemical Communications (Cambridge, England)
|April 22, 2003
Abstract:
The first authenticated example of migration of a methyl group from palladium(II) to a coordinated N-heterocyclic carbene is described.