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A Customizable Approach for the Enzymatic Production and Purification of Diterpenoid Natural Products
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Three new jatrophane-type diterpenes from Euphorbia pubescens

Cláudia Valente1, Maria José Ferreira, Pedro M Abreu

  • 1Centro de Estudos de Ciências Farmacêuticas, Faculdade de Farmácia da Universidade de Lisboa, Lisboa, Portugal.

Planta Medica
|April 24, 2003
PubMed

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Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...
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Removing one hydrogen from the intervening CH2 group with both...
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