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All-metal antiaromatic molecule: rectangular Al4(4-) in the Li3Al4(-) anion

Aleksey E Kuznetsov1, K Alexander Birch, Alexander I Boldyrev

  • 1Department of Chemistry and Biochemistry, Utah State University, Logan, UT 84322, USA.

Science (New York, N.Y.)
|April 26, 2003
PubMed
Summary

Researchers experimentally and theoretically characterized antiaromaticity in the all-metal Li3Al4(-) system. This finding, revealed by photoelectron spectroscopy and ab initio calculations, highlights a unique electronic structure in this novel compound.

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