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Updated: Jul 19, 2026

Controlling the Size, Shape and Stability of Supramolecular Polymers in Water
Published on: August 2, 2012
Size-selective organization of enthalpic compatibilized nanocrystals in ternary block copolymer/particle mixtures
Michael R Bockstaller1, Yonit Lapetnikov, Shlomo Margel
1Department of Materials Science and Engineering, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA.
Abstract:
Dependent on the relative particle core size, two distinct types of particle topologies in block copolymer/nanocrystal blends have been identified, that is, the localization of particles along the intermaterial dividing surface or at the center of the respective polymer domain. In ternary systems consisting of block copolymer and two different-sized nanocrystal species, the distinct morphological types are conserved, resulting in autonomous size-selective separation and organization of the respective nanocrystals within alternating arrays and sheets.
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