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Novel carbonyl allylation mediated by SnCl2/TiCl3 in water
Xiang-Hui Tan1, Bo Shen, Wei Deng
1Department of Chemistry, University of Science and Technology of China, Hefei 230026, China.
Organic Letters
|May 24, 2003
Abstract:
[reaction: see text] Under the Lewis acid catalysis offered by TiCl(3), SnCl(2) can efficiently mediate the aqueous Barbier reactions between aldehydes and allyl chloride or bromide.