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Cyclization of aryl acyl radicals generated from S-(4-cyano)phenyl thiolesters by a nickel complex catalyzed
Shigeko Ozaki1, Masashi Adachi, Sayaka Sekiya
1Graduate School of Pharmaceutical Sciences, Osaka University, 1-6, Yamadaoka, Suita, Japan. ozaki@phs.osaka-u.ac.jp
The Journal of Organic Chemistry
|May 24, 2003
Abstract:
Aromatic acyl radicals generated from S-(4-cyano)phenyl 2-alkenylthiobenzoate by a nickel complex catalyzed electroreduction undergo 5- and 6-exo cyclization to give 1-indanone and dihydro-1-naphthalenone derivatives, respectively.