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Coordination polymers based on square planar Co(II) node and linear spacer: solvent-dependent pseudo-polymorphism and
Dong Mok Shin1, In Su Lee, Young Keun Chung
1School of Chemistry, Center for Molecular Catalysis, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Chemical Communications (Cambridge, England)
|May 30, 2003
Abstract:
Reaction of Co(NCS)2 with 1-methyl-1'-(4-pyridyl)-2-(4-pyrimidyl)ethylene (mppe) in different solvents yields two kinds of novel coordination polymer structures of [Co(mppe)2(NCS)2]n: one of them shows an unprecedented interpenetrating structure with both 2D and 3D topological isomers.