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Dicationic [(BINAP)Pd(solvent)2]2+[TfO-]2: enantioselective hydroamination catalyst for alkenoyl-N-oxazolidinones
1Department of Chemistry, King's College London, Strand, London WC2R 2LS, UK.
Chemical Communications (Cambridge, England)
|June 5, 2003
Abstract:
Dicationic (BINAP)palladium(II) complex induced high enantioselectiviies in the addition of primary (and secondary) aromatic amines to alpha,beta-unsaturated oxazolidinones (up to 93% ee).