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Osmium replica of mesoporous silicate MCM-48: efficient and reusable catalyst for oxidative cleavage and
Kwangyeol Lee1, Yong-Ho Kim, Soo Bong Han
1Department of Chemistry and School of Molecular Science (BK 21), Korea Advanced Institute of Science and Technology (KAIST), Daejeon, 305-701, Korea.
Abstract:
A three-dimensional networked osmium nanomaterial (N-Os) was prepared by a thermal decomposition of Os3(CO)12 within mesopores of MCM-48. The novel N-Os species shows high catalytic activity and excellent reusability in the oxidation reactions of unsaturated compounds under mild conditions.
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