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Bis(2-aminopyridine-kappaN(1))(benzoato-kappaO)silver(I)
Hai-Liang Zhu1, Anwar Usman, Hoong-Kun Fun
1Department of Environmental and Chemical Engineering, Wuhan University of Science and Engineering, Wuhan 430073, People's Republic of China.
Abstract:
In the title compound, [Ag(C(7)H(5)O(2))(C(5)H(6)N(2))(2)], the Ag(I) atom is tricoordinated by two independent pyridine N atoms and one benzoate O atom in a nearly planar geometry. An intramolecular N-H.O hydrogen bond forms an S(8) graph ring. The packing is built from molecular layers stabilized by two types of N-H.O hydrogen bond. Intermolecular Ag.N and intramolecular Ag.O contacts were also observed, together with three weak intermolecular C-H.pi interactions.