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Estimating soil phosphorus requirements and limits from oxalate extract data.

E M D'Angelo1, M V Vandiviere, W O Thom

  • 1University of Kentucky, Soil & Water Biogeochemistry Laboratory, Dep. of Agronomy, N-122 Agricultural Science Building North, Lexington, KY 40546-0091, USA. edangelo@uky.edu

Journal of Environmental Quality
|June 18, 2003
PubMed
Summary

Excessive phosphorus inputs cause eutrophication. A new soil test using oxalate-extractable aluminum and iron accurately predicts phosphorus requirements, helping manage soil fertility and water quality.

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Area of Science:

  • Environmental Chemistry
  • Soil Science
  • Agricultural Science

Background:

  • Excessive phosphorus (P) from fertilizers and manure contributes to freshwater eutrophication via soil solution and runoff.
  • Current methods for assessing runoff P, like soil test P and P sorption saturation, have limitations across diverse soil types and routine application.

Purpose of the Study:

  • To identify easily measurable soil characteristics correlated with soil phosphorus requirements (P(req)).
  • To develop a reliable method for determining soil phosphorus limits (PL) to prevent nutrient runoff.

Main Methods:

  • Determined P(req) for 18 diverse soils using sorption isotherm data, correcting for native sorbed P.
  • Correlated P(req) with the sum of oxalate-extractable aluminum (Al) and iron (Fe).

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  • Calculated PL by subtracting native sorbed P from P(req) to target specific solution P levels.
  • Main Results:

    • P(req) strongly correlated with the sum of oxalate-extractable Al and Fe (R2 > 0.90).
    • Calculated PL values ranged from -92 to 253 mg P kg(-1), indicating P surplus or deficiency.
    • Oxalate extracts of P, Al, and Fe showed potential for determining PL up to 10 mg P L(-1).

    Conclusions:

    • Oxalate-extractable Al and Fe provide a robust indicator for soil phosphorus requirements.
    • The soil oxalate extraction test can be integrated into best management practices for soil fertility and water quality protection.
    • This method offers a practical approach to managing phosphorus inputs and mitigating eutrophication risks.