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Functionalizing the surface of II-VI clusters: redox active centres on the adamantoid complex
Terry P Lebold1, Donald L B Stringle, Mark S Workentin
1Department of Chemistry, The University of Western Ontario, London N6A 5B7, Canada.
Chemical Communications (Cambridge, England)
|July 5, 2003
Abstract:
Trimethylsilylselenoferrocene 1 has been prepared in good yield. The reactive silyl group on 1 is used as a driving force for the synthesis [Cl4Cd4[mu2-Se(C5H4)Fe(C5H5))6]2- 2, a Cd4Se6 adamantoid cluster with six surface ferrocenyl groups.