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Related Experiment Videos

Polymeric (O-ethyl dithiocarbonato)silver(I).

Irene Ara1, Fatima El Bahij, Mohamed Lachkar

  • 1Departamento de Química Inorgánica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, 50009 Zaragoza, Spain. irene.ara@posta.unizar.es

Acta Crystallographica. Section C, Crystal Structure Communications
|July 12, 2003
PubMed
Summary
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This study reveals a polymeric layered structure for the silver xanthate compound [Ag(C(3)H(5)OS(2))](n). Silver atoms exhibit five-coordination, forming a two-dimensional network of condensed metallacycles.

Area of Science:

  • Solid-state chemistry
  • Coordination chemistry
  • Materials science

Background:

  • Polymeric coordination compounds offer unique structural motifs and properties.
  • Silver-organic frameworks are of interest for various applications.
  • Xanthate ligands provide versatile coordination modes.

Purpose of the Study:

  • To elucidate the solid-state structure of the title silver xanthate compound, [Ag(C(3)H(5)OS(2))](n).
  • To characterize the coordination environment and bonding interactions within the material.

Main Methods:

  • Single-crystal X-ray diffraction analysis was employed to determine the crystal structure.
  • Analysis of coordination numbers and bond distances/angles provided insights into bonding.

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Main Results:

  • The compound exhibits a polymeric layered structure in the solid state.
  • Each silver (Ag) atom is five-coordinated in a distorted trigonal-bipyramidal geometry.
  • The structure features a two-dimensional network of condensed six- and eight-atom metallacycles formed by silver and xanthate ligands.

Conclusions:

  • The silver xanthate compound forms an extended polymeric network with specific coordination preferences.
  • The observed layered structure arises from the interplay of silver-sulfur coordination and bridging xanthate ligands.