A novel bilayer cobalt(II)-organic framework with nanoscale channels accommodating large organic molecules
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Published on: July 10, 2017
Junhua Luo1, Maochun Hong, Ruihu Wang
1State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Abstract:
A unique noninterpenetrated 2D bilayer cobalt(II)-organic framework, [[Co(dpe)(NO(2)-BDC)].0.5(dpe)](n).nH(2)O (1), possessing nanoscale rectangular channels that clathrate large organic molecules, has been hydrothermally synthesized by reaction of cobalt(II) salt with 5-nitro-1,3-benzenedicarboxylic acid (NO(2)-H(2)BDC) and 1,2-bis(4-pyridyl)ethylene (dpe).
