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A novel bilayer cobalt(II)-organic framework with nanoscale channels accommodating large organic molecules
Junhua Luo1, Maochun Hong, Ruihu Wang
1State Key Laboratory of Structural Chemistry, Fujian Institute of the Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Inorganic Chemistry
|July 23, 2003
Abstract:
A unique noninterpenetrated 2D bilayer cobalt(II)-organic framework, [[Co(dpe)(NO(2)-BDC)].0.5(dpe)](n).nH(2)O (1), possessing nanoscale rectangular channels that clathrate large organic molecules, has been hydrothermally synthesized by reaction of cobalt(II) salt with 5-nitro-1,3-benzenedicarboxylic acid (NO(2)-H(2)BDC) and 1,2-bis(4-pyridyl)ethylene (dpe).