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Molecular Weight of Step-Growth Polymers01:08

Molecular Weight of Step-Growth Polymers

Step growth polymerization involves bi or multifunctional monomers. Bifunctional monomers react to form linear step growth polymers, whereas multifunctional monomers react to form non-linear or branched polymers.
As the step-growth polymerization involves step-wise condensation of monomers, the molecular weight also builds up eventually. Consequently, high molecular weight polymers are obtained at the late stages of the polymerization, where 99% of monomers have been consumed.
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The shape of a small drop of liquid can be considered spherical, neglecting the effect of gravity. This drop can further be considered as two equal hemispherical drops put together due to surface tension. The forces acting on the spherical drop are due to the pressure of the liquid inside the drop, the pressure due to air outside the drop, and the force due to the surface tension acting on the two hemispherical drops.
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Mathematical Modeling: Problem Solving

Mathematical modeling transforms real-world scenarios into mathematical expressions, allowing for structured problem-solving and analysis. This process involves defining the situation, assigning variables to measurable quantities, selecting an appropriate model, and solving the resulting equation. Such models are invaluable in finance, providing precise methods to evaluate investments, loans, and repayment structures.A widely used example is the calculation of fixed monthly payments on a loan,...

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Related Experiment Video

Updated: Jul 17, 2026

Microfluidic Devices for Characterizing Pore-scale Event Processes in Porous Media for Oil Recovery Applications
08:38

Microfluidic Devices for Characterizing Pore-scale Event Processes in Porous Media for Oil Recovery Applications

Published on: January 16, 2018

A mathematical model for an expanding foam.

L W Schwartz1, R V Roy

  • 1Department of Mechanical Engineering, University of Delaware, Newark, DE 19716-3140, USA. schwartz@me.udel.edu

Journal of Colloid and Interface Science
|July 30, 2003
PubMed
Summary

This study models foam film thinning, revealing surfactant concentration as key to controlling final film thickness. Sufficient surfactant ensures uniform film dilation during foam expansion.

Area of Science:

  • Fluid dynamics
  • Materials science
  • Chemical engineering

Background:

  • Foams are ubiquitous in nature and industry.
  • Understanding thin liquid film dynamics is crucial for foam stability and performance.
  • Existing models often lack detailed consideration of dynamic expansion processes.

Purpose of the Study:

  • To develop a theoretical and numerical model for the shape evolution of thin liquid films in foams.
  • To investigate the influence of foam expansion and surfactant concentration on film dynamics.
  • To reproduce known features of expanding foams using the developed model.

Main Methods:

  • Formulation of a theoretical model for thin liquid film evolution.
  • Numerical solution of three coupled partial differential equations.

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Preparation of Carbon Fiber and Bamboo Fiber Reinforced Poly (butylene Adipate-co-terephthalate) Foams by Supercritical Carbon Dioxide Foaming
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  • Inclusion of two distinct time scales: process time and drying/curing time.
  • Analysis of capillary action, surface tension gradients, and foam expansion effects.
  • Main Results:

    • Identified surfactant amount as the dominant factor controlling final film thickness.
    • Demonstrated uniform spatial dilation of films when sufficient surfactant is present.
    • Successfully reproduced several characteristic behaviors of expanding foams.
    • The model incorporates both process and drying/curing time scales.

    Conclusions:

    • Surfactant concentration is a critical parameter for controlling foam film thickness and stability.
    • The developed model accurately captures the complex dynamics of expanding foam films.
    • The findings have implications for foam applications in various industries, including materials processing and product formulation.