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Stacking-fault nucleation on Ir(111).

Carsten Busse1, Celia Polop, Michael Müller

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Scanning tunneling microscopy reveals that iridium (Ir) crystal growth on Ir(111) surfaces forms stacking faults. An atomistic model explains this phenomenon by adatom clusters occupying hexagonal close-packed (hcp) sites.

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Area of Science:

  • Surface science
  • Materials science
  • Condensed matter physics

Background:

  • Homoepitaxial growth is crucial for thin film fabrication.
  • Understanding crystal stacking sequences (fcc vs. hcp) is key to controlling material properties.
  • Stacking faults can significantly alter surface and bulk material characteristics.

Purpose of the Study:

  • To investigate the nucleation and growth mechanisms of stacking faults during Ir(111) homoepitaxy.
  • To develop an atomistic model explaining the formation of stacking faults based on experimental observations.
  • To validate the model using independent experimental parameters and assess its general applicability.

Main Methods:

  • Variable temperature scanning tunneling microscopy (STM) was employed to observe island formation.
  • Analysis of island nucleation and growth as a function of deposition temperature.
  • Field ion microscopy (FIM) was used to derive independent parameters for model validation.

Main Results:

  • Islands nucleate and grow in both regular face-centered cubic (fcc) and faulted hexagonal close-packed (hcp) stacking configurations.
  • Stacking fault formation is linked to the behavior of mobile adatom clusters occupying hcp sites.
  • The developed atomistic model accurately describes the experimental results for Ir(111) growth.

Conclusions:

  • The study provides a detailed atomistic understanding of stacking-fault formation during Ir(111) homoepitaxy.
  • Mobile adatom clusters occupying hcp sites play a critical role in the growth of metastable stacking-fault islands.
  • The proposed model is validated and expected to be applicable to other surface systems.