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Tandem RCM-Pauson-Khand reaction for access to tricycles in one step
Marta Rosillo1, Luis Casarrubios, Gema Domínguez
1Departamento de Química, Facultad de CC, Experimentales y de la Salud, Universidad San Pablo-CEU, Boadilla del Monte, 28668-Madrid, Spain.
Organic & Biomolecular Chemistry
|August 21, 2003
Abstract:
Starting from conveniently designed dienynes complexed to cobalt, a tandem RCM-intramolecular Pauson-Khand reaction yields tricyclic compounds. The methodology allows the synthesis of 6,5,5 and 7,5,5 systems.