Related Experiment Video
Updated: Aug 16, 2026

Facile Preparation of Internally Self-assembled Lipid Particles Stabilized by Carbon Nanotubes
Published on: February 19, 2016
Preferential precipitation of C70 over C60 with p-halohomooxacalix[3]arenes
1Department of Chemistry, Graduate School of Science, Kyoto University, Kitashirakawa, Sakyo-ku, Kyoto 606-8502, Japan.
Abstract:
Preferential precipitation of C70 from a toluene solution of C60 and C70 was accomplished with p-trihalohomooxacalix[3]arenes (1(3).X.X.X) prepared by the reductive coupling of diformylphenols. Heavy halogens, Br and/or I, are essential at the para position of 1(3).X.X.X for obtaining good yields and selectivities. C70 with up to 92% purity was obtained after the preferential precipitation.
More Related Videos
Related Concept Videos
C4 Pathway and CAM
C4 Pathway
The C4 pathway is used by plants such as...
Regioselectivity of Electrophilic Additions to Alkenes: Markovnikov's Rule
The hydrohalogenation of an unsymmetrical alkene can yield two haloalkane products, depending on which vinylic carbon takes up the halogen. However, one product usually predominates, where hydrogen adds to the vinylic carbon bearing the...
Formation of Halohydrin from Alkenes
Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration
Preparation of Diols and Pinacol Rearrangement
The reaction begins with transferring a proton from the acid catalyst to one of the hydroxyl groups, producing an oxonium ion.
Electrophilic 1,2- and 1,4-Addition of HX to 1,3-Butadiene

