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Synthesis and Purification of Iodoaziridines Involving Quantitative Selection of the Optimal Stationary Phase for Chromatography
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[Determination of trace iodine based on kinetic-spectrophotometry with malachite green-chloramine T system]
1Department of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215006, China.
Abstract:
In this paper, a new kinetic-spectrophotometric method for the determination of trace amount of iodine has been proposed. It is based on the iodine catalysed the reaction of malachite green oxidized by chloramine T in hydrochloric acid medium. The method is sensitive, simple and with good selectivity. The linear range of determination of iodine is 0-48 micrograms.L-1, the detection limit is 4.9 x 10(-10) g.mL-1. The method has been used for the determination of trace amount of iodine in food with satisfactory results.
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